CO-O-F Series

What is COF 366-co and cof-367-co?

In this research, two frameworks (COF-366-Co and COF-367-Co) were prepared through the condensation of 5,10,15,20-tetrakis (4-aminophenyl)porphinato]cobalt [Co (TAP)] with two different aldehydes ( Figure 2a ).

What are COF materials?

In most of the previous reviews, COFs are typically categorized as one kind of organic framework material, [ 65, 66] 2D materials, [ 67] or heterogeneous molecular catalysts [ 21], and are discussed together with other materials.

What is the difference between COF and C 2+ products?

Although COFs have been extensively studied for ECO 2 RR catalysis with significant achievements, most of the products are the easily obtained two-electron reduced product, CO. In contrast, C 2+ products impose more stringent requirements on reaction kinetics.

What is a 2D COF based on a metalloporphyrin monomer?

Jiang on another occasion, also prepared 2D COFs series composed of metalloporphyrin monomer (MP, M= H 2, Cu, Ni). 213 Structurally, the COFs possess intralayer hydrogen bonding that function to interlock the tetragonal sheet of the COFs in planar confirmation via π-cloud delocalization over the 2D sheets.

Are COFs a good catalyst for eco 2 RR?

As an emerging class of porous materials, COFs have been used in the ECO 2 RR domain and demonstrated exceptional performance. This review presents the latest developments of COFs as ECO 2 RR catalysts and provides systematic summaries based on the characteristics of COFs materials.

Does co-COF have a supereminent photocatalytic performance with CO-O 4 sites?

Mechanistic investigations indicate that the supereminent photocatalytic performance of Co-COF with Co-O 4 sites is mainly attributed to the strong separation ability of photoinduced electrons and holes although the contributions of high CO 2 adsorption capacity and low charge-transfer resistance are also important.